Edit: Disregard my post, I'm thinking backwards. Crow is tasty today.
You have the action correct, but your forces backwards. The faster the wheel spins, the more the valve core wants to fly towards the outside and therefore open.
Nope, sorry, it's you that's thinking in reverse. A valve stem points outwards, centrifugal force adds outwards force. The valve stem pin requires
inward force (opposite the centrifugal force) to open the valve.
The faster the vehicle goes, the tighter the valve stem seals.
Yes, the valve
assembly is being pulled outwards, but remember, the assembly itself is not what physically opens to allow the air, it's an internal mechanism inside it again (that being the
valve part of the valve stem) that again, and that's designed to tighten with centrifugal force, not open. The assembly is threaded into the stem and if there's a failure or problem there (bad seal on the valve assembly, or bad face on the stem where it seats) that would indeed cause a leak, but it wouldn't be sudden like that, it would be constant.
Op needs to do a soap test on the entire tire, rim, valve etc etc and find out where the leak originates, as others have suggested.