Will it even shoot air out if you're not pressing down on a valve stem?
Can't you use the master cylinder on the bike to push it out? I guess you have the caliper off already?
The piston is seized up somehow, the MC pushes it 1/4". That's why I took the caliper out to clean up whatever crud is in there
It'll blow it across the street! Good way to damage a piston or loose a finger/eye. 10psi will blow them out with LOTS of force.