DO NOT use a penny as a washer on a head bolt.
1) Pennys are copper coated not made of copper
2)The relief (the pattern on the penny) will screw your torque ratings.
You are going to be hard pressed to find copper washers in metric sizes, most hydraulics, where copper washers are typically used, are imperial.
If you had a chunk of copper I could make you one.
I see no reason that those hold down bolts have copper washers. If you're trying to seal, you got other problems. I would use hardened steel washers (I would also replace the cap screws with studs. Studs work better for "hold down").
When I asked "does it matter?" I was asking if the washer knew the difference of what it was to be used on. (NO it doesn't).